Composition modulation and nanophase separation in a binary epilayer

When a thin binary layer grows epitaxially on an elemental substrate, the composition often modulates in the plane of the layer. The layer may even demix when the bulk of the same composition is miscible. Sometimes the layer separates into two phases, forming periodic stripes or other regular patterns. The size of the separated phases may be in the range 1±100 nm, and stable against coarsening on annealing. This paper develops a thermodynamic framework to study these remarkable phenomena. For an epilayer less than a few monolayers thick, the excess energy cannot be attributed to individual sources of super®cial mis®t. Instead, we lump the epilayer and adjacent monolayers of the substrate into a single super®cial object, and specify the excess surface energy for the object. The variation of the surface energy density with the variation of the strain de®nes surface stress. When the composition modulates in the epilayer, the surface stress is nonuniform, deforms the substrate, and reduces the total energy. Consequently, the composition-dependent surface stress tends to re®ne phases, resisting coarsening. In a stability analysis, we perturb a uniform concentration ®eld into a sinusoidal ®eld with a small amplitude and an arbitrary wavelength. The entropy of mixing stabilizes the uniform layer for long wavelengths. To stabilize the uniform layer for short wavelengths, we assume that the surface energy density also depends on concentration-gradient. A stability condition shows the combined elastic, entropic, and gradient e€ects. We also outline a dynamical system, which can be used to study pattern emergence and evolution during annealing. # 2000 Elsevier Science Ltd. All rights reserved. 0022-5096/00/$ see front matter # 2000 Elsevier Science Ltd. All rights reserved. PII: S0022 -5096 (99)00038 -1 Journal of the Mechanics and Physics of Solids